SAES-422 Multistate Research Activity Accomplishments Report

Status: Approved

Basic Information

Participants

Harsh, James (harsh@wsu.edu) - Washington State University; Gimenez, Daniel (gimenez@envsci.rutgers.edu) - Rutgers University; Hetteriachchi, Ganga (ganga@ksu.edu) - Kansas State University; Xia, Kang (kx6@msstate.edu) - Mississippi State University; Alvin Smucker (smucker@msu.edu); Sparks, Donald (dlsparks@udel.edu) - University of Delaware; Zhang, Wei (weizhang@msu.edu) - Michigan State University.

NC-1187 Meeting November 3, 2014 Long Beach Residence Inn 1. Attendees are listed in the "Participants" section. Because of the location and conflicting meetings, there were a few members who were not able to make it to the meeting. They did, however, interact with the chair or advisor on site to contribute to discussion items. 2. Project NC-1187 requires a proposal for renewal this year. As a result, the meeting was used to discuss desired changes in the new proposal and milestones for new products. It was noticed that the objectives in the posted proposal are not ours and Harsh will contact Christina Hamilton to get it fixed. 3. The group decided to leave the first objective as is and add detail to others. 4. One objective needs to emphasize spatial and temporal scales and pushing the limit of resolution below nm scale. 5. Be sure to specify opportunities at the new Brookhaven light source. Emphasize the new capabilities and state that we will take advantage of lines as they become available starting Fall, 2015. 6. Keep the milestone to produce a “white paper” that can serve as a seed to seek extramural funding. Need to decide to whom this should be addressed. 7. Plan for a symposium in Minnesota that emphasizes use of synchrontron sources but also other state of the art capabilities applicable to particle behavior and characterization. This could be a joint symposium including soil chemistry, soil physics, and/or soil mineralogy. Dan Strawn is chair of Soil Chemistry; Markus Flury Chair of Soil Physics; Daniel Hirmas Chair of Soil Mineralogy. 8.Keep milestone of multi-investigator proposal for group. 9. Daniel Gimenez will draft the proposal and send by email to all participants for comments before submitting.

Accomplishments

Outputs: 1. A soot particle aerosol mass spectrometer (SP-AMS) was used to measure the chemical composition of particulate emitted by gasoline and diesel vehicles at high time resolution and allowed distinction between carbon derived from fuel and lubricant sources. 2. For improved chemical characterization of the organic composition of ambient particulate matter, a combined thermal desorption aerosol gas chromatograph-aerosol mass spectrometer (TAG-AMS) was developed allowing simultaneous and complementary measurements of quantitative organic mass loading and detailed organic speciation. With a high-resolution time-of-flight mass spectrometer (HR-ToF-MS), elemental-level determination of OA oxidation state and improved compound identification and separation of unresolved complex mixtures are enabled. Such measurements will improve the identification of organic constituents of ambient aerosol and contribute to the ability of atmospheric chemistry models to predict ambient aerosol composition and loadings. 3. A patent was applied for describing a nanocomposite structure for a sensor that can serve as a building block for surface enhanced Raman scattering substrates. 4. To improve exposure characterization of resuspended aerosol PM, a mobile sampler--"Pre-toddler Inhalable Particulate Environmental Robotic (PIPER)"--was developed. Measurements of PM and its constituents with PIPER are more strongly associated with asthma, eczema and wheeze compared with measurements using SIMs. Application of this methodology may provide useful insights into early childhood exposures related to the etiology of childhood illnesses associated with inhalation exposures. 5. A stepwise, multiobjective, multivariable automatic calibration method for the Agricultural Environmental Policy eXtender (APEX) model for simulating runoff, sediment, total phosphorus (TP), and total nitrogen (TN) was developed. This is a cost efficient technique that should be of significant benefit to modelers. 6. Researchers developed, calibrated, and validated a fuzzy rainfall-runoff model using long-term data of three adjacent field scale row crop watersheds (1.65-4.44 ha) with intermittent discharge in the claypan soils of Northeast Missouri. The fuzzy rainfall-runoff model has the potential for runoff predictions at field-scale watersheds with minimum input. It also could up-scale the predictions for large-scale watersheds to evaluate the benefits of conservation practices. 7. An environmentally benign remediation method was found effective for phenol and heavy metal removal from contaminated water. The product is a combination of corn cob silica, alginate, and bacteria immobilized into beads. 8. Several studies examined the basic science of colloid transport in the vadose zone. a. An examination of the role of fracking flow-back fluids in colloid mobilization from sand showed that the fluid remobilized in situ colloids via 1) surface tension reduction and steric repulsion and 2) slow kinetic disaggregation of colloid flocs. Increasing the flow rate of the flowback fluid mobilized an additional 36% of colloids, due to the expansion of water filled pore space. This study suggests that hydrofracking fluid may also indirectly contaminate groundwater by remobilizing existing colloidal pollutants. b. Transport and retention of polyvinylpyrrolidone (PVP)-coated silver nanoparticles (PVP-AgNPs) were investigated over a wide range of physicochemical factors in water-saturated columns packed with an Ultisol rich in clay-size particles. The transport and retention of PVP-AgNPs are highly sensitive to physicochemical factors, but mathematical modeling was found to accurately predict the fate of these ENPs in porous media. c. Redistribution of E. coli within soil aggregates was studied as a function of management practices. E. coli movement in soil aggregates was mainly driven by water flow via capillary forces and redistribution was most pronounced in conventional tillage aggregates, followed by no-till, and was almost negligible in native vegetation soil aggregates. d. A geocentrifuge was use to determine if water content or flow rate is more important for colloid transport. Negatively charged polystyrene colloids (220 nm diameter) through unsaturated sand-filled columns under steady-state flow at different water contents and flow rates. Colloid transport decreased with decreasing water content, and below a critical water content, colloid transport was inhibited, and colloids were strained in water films. The flow rate affected retention of colloids in the secondary energy minimum, with less colloids being trapped when the flow rate increased. These results confirm the importance of both water content and flow rate for colloid transport in unsaturated porous media and highlight the dominant role of water content. 9. Other research within NC-1187 considered the distribution and characterization of aerosol particles over urban and rural areas. One showed the importance of vehicle lubricants was an important contributor to organic aerosols in addition to fuels. Another examined organic matter in the atmosphere above Bakersfield, Pasadena, Tijuana, and on board the R/V Atlantis. They found that 60-88% of the total OM was attributed to fossil fuel burning. Additional marine, vegetative detritus, and biomass burning or biogenic sources contribute up to 40% of the OM. A study of aerosol amines over a southeastern U.S. forested site and a polluted midwestern site. Amines were concentrated on particulate matter, were dependent on temperature and biomass burning events, and were higher at the polluted site. The study concluded that gas to particle conversion was a concentration determining process at the forested site and the importance of anthropogenic emission sources. 10. The dispersion of Fe from deep sea vents was studied from the perspective of Fe-organic complexes. It was found that Fe is scavenged and taken up by microorganisms providing the source of organic matter for complexation. The authors state "cellular iron uptake is a major process in plume microbial communities and suggest new mechanisms for generating Fe-C complexes. This 'microbial iron pump' could represent an important mode of converting hydrothermal iron into bioavailable forms that can be dispersed throughout the oceans." Another study involving Fe-organic interactions showed that Mariprofundus ferrooxydans, which produces strands of ferrihydrite, may use extracellular polysaccharides as templates for ferrihydrite precipitation which is then followed by adsorption of dissolved organic carbon preserving the morphological structure of the Fe mineral. There were no new milestones or activities in 2014.

Impacts

  1. A soot particle aerosol mass spectrometer (SP-AMS) was used to measure the chemical composition of particulate emitted by gasoline and diesel vehicles at high time resolution and allowed distinction between carbon derived from fuel and lubricant sources.
  2. For improved chemical characterization of the organic composition of ambient particulate matter, a combined thermal desorption aerosol gas chromatograph-aerosol mass spectrometer (TAG-AMS) was developed allowing simultaneous and complementary measurements of quantitative organic mass loading and detailed organic speciation.
  3. A patent was applied for describing a nanocomposite structure for a sensor that can serve as a building block for surface enhanced Raman scattering substrates. This could greatly improve detection limits for the technique.
  4. To improve exposure characterization of resuspended aerosol PM, a mobile sampler--"Pre-toddler Inhalable Particulate Environmental Robotic (PIPER)"--was developed. Measurements of PM and its constituents with PIPER are more strongly associated with asthma, eczema and wheeze compared with measurements using SIMs. Application of this methodology may provide useful insights into early childhood exposures related to the etiology of childhood illnesses associated with inhalation exposures.
  5. A stepwise, multiobjective, multivariable automatic calibration method for the Agricultural Environmental Policy eXtender (APEX) model for simulating runoff, sediment, total phosphorus (TP), and total nitrogen (TN) was developed. This is a cost efficient technique that should be of significant benefit to modelers.
  6. A fuzzy rainfall-runoff model was developed with the potential for runoff predictions at field-scale watersheds with minimum input. It also could up-scale the predictions for large-scale watersheds to evaluate the benefits of conservation practices.
  7. An environmentally benign remediation method was found effective for phenol and heavy metal removal from contaminated water. The product is a combination of corn cob silica, alginate, and bacteria immobilized into beads.

Publications

1. Aramrak, S.; Flury, M.; Harsh, J. B.; Zollars, R. L., Colloid Mobilization and Transport during Capillary Fringe Fluctuations. Environmental Science & Technology 2014, 48, (13), 7272-7279. 2. Ash, P. W.; Boyd, D. A.; Hyde, T. I.; Keating, J. L.; Randlshofer, G.; Rothenbacher, K.; Sankar, G.; Schauer, J. J.; Shafer, M. M.; Toner, B. M., Local Structure and Speciation of Platinum in Fresh and Road-Aged North American Sourced Vehicle Emissions Catalysts: An X-ray Absorption Spectroscopic Study. Environmental Science & Technology 2014, 48, (7), 3658-3665. 3. Atkinson, C.; Pechanova, O.; Sparks, D. L.; Brown, A.; Rodriguez, J. M., Differentiation of Aflatoxigenic and Non-Aflatoxigenic Strains of Aspergilli by FT-IR Spectroscopy. Applied Spectroscopy 2014, 68, (8), 920-924. 4. Attanayake, C. P.; Hettiarachchi, G. M.; Harms, A.; Presley, D.; Martin, S.; Pierzynski, G. M., Field Evaluations on Soil Plant Transfer of Lead from an Urban Garden Soil. Journal of Environmental Quality 2014, 43, (2), 475-487. 5. Babu, A. G.; Shea, P. J.; Oh, B.-T., Trichoderma sp PDR1-7 promotes Pinus sylvestris reforestation of lead-contaminated mine tailing sites. Science of the Total Environment 2014, 476, 561-567. 6. Babu, A. G.; Shim, J.; Bang, K.-S.; Shea, P. J.; Oh, B.-T., Trichoderma virens PDR-28: A heavy metal-tolerant and plant growth-promoting fungus for remediation and bioenergy crop production on mine tailing soil. Journal of Environmental Management 2014, 132, 129-134. 7. Babu, A. G.; Shim, J.; Shea, P. J.; Oh, B.-T., Penicillium aculeatum PDR-4 and Trichoderma sp PDR-16 promote phytoremediation of mine tailing soil and bioenergy production with sorghum-sudangrass. Ecological Engineering 2014, 69, 186-191. 8. Baker, L. L.; Nickerson, R. D.; Strawn, D. G., XAFS STUDY OF Fe-SUBSTITUTED ALLOPHANE AND IMOGOLITE. Clays and Clay Minerals 2014, 62, (1-2), 20-34. 9. Baker, L. L.; Strawn, D. G., TEMPERATURE EFFECTS ON THE CRYSTALLINITY OF SYNTHETIC NONTRONITE AND IMPLICATIONS FOR NONTRONITE FORMATION IN COLUMBIA RIVER BASALTS. Clays and Clay Minerals 2014, 62, (1-2), 89-101. 10. Baker, L. R.; Pierzynski, G. M.; Hettiarachchi, G. M.; Scheckel, K. G.; Newville, M., Micro-X-Ray Fluorescence, Micro-X-Ray Absorption Spectroscopy, and Micro-X-Ray Diffraction Investigation of Lead Speciation after the Addition of Different Phosphorus Amendments to a Smelter-Contaminated Soil. Journal of Environmental Quality 2014, 43, (2), 488-497. 11. Bennett, S. A.; Toner, B. M.; Barco, R.; Edwards, K. J., Carbon adsorption onto Fe oxyhydroxide stalks produced by a lithotrophic iron-oxidizing bacteria. Geobiology 2014, 12, (2), 146-156. 12. Chen, C.; Dynes, J. J.; Wang, J.; Karunakaran, C.; Sparks, D. L., Soft X-ray Spectronnicroscopy Study of Mineral-Organic Matter Associations in Pasture Soil Clay Fractions. Environmental Science & Technology 2014, 48, (12), 6678-6686. 13. Chimchart, B.; Kheoruenromne, I.; Suddhiprakarn, A.; Sparks, D. L., Role of Organic Matter on Charge Behavior of Oxisols and Ultisols Under Tropical Savanna and Tropical Monsoon Climates in Thailand. Soil Science 2013, 178, (10), 540-549. 14. Dallmann, T. R.; Onasch, T. B.; Kirchstetter, T. W.; Worton, D. R.; Fortner, E. C.; Herndon, S. C.; Wood, E. C.; Franklin, J. P.; Worsnop, D. R.; Goldstein, A. H.; Harley, R. A., Characterization of particulate matter emissions from on-road gasoline and diesel vehicles using a soot particle aerosol mass spectrometer. Atmospheric Chemistry and Physics 2014, 14, (14), 7585-7599. 15. Dickson, J. O.; Harsh, J. B.; Flury, M.; Lukens, W. W.; Pierce, E. M., Competitive Incorporation of Perrhenate and Nitrate into Sodalite. Environmental Science & Technology 2014, 48, (21), 12851-12857. 16. Elbana, T. A.; Sparks, D. L.; Selim, H. M., Transport of Tin and Lead in Soils: Miscible Displacement Experiments and Second-Order Modeling. Soil Science Society of America Journal 2014, 78, (3), 701-712. 17. Fahrenfeld, N.; Knowlton, K.; Krometis, L. A.; Hession, W. C.; Xia, K.; Lipscomb, E.; Libuit, K.; Green, B. L.; Pruden, A., Effect of Manure Application on Abundance of Antibiotic Resistance Genes and Their Attenuation Rates in Soil: Field-Scale Mass Balance Approach. Environmental Science & Technology 2014, 48, (5), 2643-2650. 18. Fan, J.-X.; Wang, Y.-J.; Liu, C.; Wang, L.-H.; Yang, K.; Zhou, D.-M.; Li, W.; Sparks, D. L., Effect of iron oxide reductive dissolution on the transformation and immobilization of arsenic in soils: New insights from X-ray photoelectron and X-ray absorption spectroscopy. Journal of Hazardous Materials 2014, 279, 212-219. 19. Garbuzenko, O. B.; Mainelis, G.; Taratula, O.; Minko, T., Inhalation treatment of lung cancer: the influence of composition, size and shape of nanocarriers on their lung accumulation and retention. Cancer Biology Medicine 2014, 11, (1), 44-55. 20. Gentner, D. R.; Ford, T. B.; Guha, A.; Boulanger, K.; Brioude, J.; Angevine, W. M.; de Gouw, J. A.; Warneke, C.; Gilman, J. B.; Ryerson, T. B.; Peischl, J.; Meinardi, S.; Blake, D. R.; Atlas, E.; Lonneman, W. A.; Kleindienst, T. E.; Beaver, M. R.; St Clair, J. M.; Wennberg, P. O.; VandenBoer, T. C.; Markovic, M. Z.; Murphy, J. G.; Harley, R. A.; Goldstein, A. H., Emissions of organic carbon and methane from petroleum and dairy operations in California's San Joaquin Valley. Atmospheric Chemistry and Physics 2014, 14, (10), 4955-4978. 21. Gentner, D. R.; Ormeno, E.; Fares, S.; Ford, T. B.; Weber, R.; Park, J. H.; Brioude, J.; Angevine, W. M.; Karlik, J. F.; Goldstein, A. H., Emissions of terpenoids, benzenoids, and other biogenic gas-phase organic compounds from agricultural crops and their potential implications for air quality. Atmospheric Chemistry and Physics 2014, 14, (11), 5393-5413. 22. Gentner, D. R.; Worton, D. R.; Isaacman, G.; Davis, L. C.; Dallmann, T. R.; Wood, E. C.; Herndon, S. C.; Goldstein, A. H.; Harley, R. A., Chemical Composition of Gas-Phase Organic Carbon Emissions from Motor Vehicles and Implications for Ozone Production. Environmental Science & Technology 2013, 47, (20), 11837-11848. 23. Grundtner, A.; Gupta, S.; Bloom, P., River Bank Materials as a Source and as Carriers of Phosphorus to Lake Pepin. Journal of Environmental Quality 2014, 43, (6), 1991-2001. 24. Gunatilake, S. R.; Craver, S.; Kwon, J.-W.; Xia, K.; Armbrust, K.; Rodriguez, J. M.; Mlsna, T. E., Analysis of Estrogens in Wastewater Using Solid-Phase Extraction, QuEChERS Cleanup, and Liquid Chromatography/Tandem Mass Spectrometry. Journal of Aoac International 2013, 96, (6), 1440-1447. 25. Guzman-Morales, J.; Frossard, A. A.; Corrigan, A. L.; Russell, L. M.; Liu, S.; Takahama, S.; Taylor, J. W.; Allan, J.; Coe, H.; Zhao, Y.; Goldstein, A. H., Estimated contributions of primary and secondary organic aerosol from fossil fuel combustion during the CalNex and Cal-Mex campaigns. Atmospheric Environment 2014, 88, 330-340. 26. Hartley, P. E.; Presley, D. R.; Ransom, M. D.; Hettiarachchi, G. M.; West, L. T., Vertisols and Vertic Properties of Soils of the Cherokee Prairies of Kansas. Soil Science Society of America Journal 2014, 78, (2), 556-566. 27. Hirmas, D. R.; Gimenez, D.; Subroy, V.; Platt, B. F., Fractal distribution of mass from the millimeter- to decimeter-scale in two soils under native and restored tallgrass prairie. Geoderma 2013, 207, 121-130. 28. Huang, Y. H.; Zhang, T. C.; Shea, P. J.; Comfort, S. D., Competitive Reduction of Nitrate, Nitrite, and Nitrobenzene in Fe-0-Water Systems. Journal of Environmental Engineering 2014, 140, (8). 29. Karathanasis, A. D., The Role of Colloidal Systems in Environmental Protection Foreword. 2014; p XV-XVI. 30. Karathanasis, A. D.; Murdock, L. W.; Matocha, C. J.; Grove, J.; Thompson, Y. L., Fragipan Horizon Fragmentation in Slaking Experiments with Amendment Materials and Ryegrass Root Tissue Extracts. Scientific World Journal 2014. 31. Karl, T.; Misztal, P. K.; Jonsson, H. H.; Shertz, S.; Goldstein, A. H.; Guenther, A. B., Airborne Flux Measurements of BVOCs above Californian Oak Forests: Experimental Investigation of Surface and Entrainment Fluxes, OH Densities, and Damkohler Numbers. Journal of the Atmospheric Sciences 2013, 70, (10), 3277-3287. 32. Kavdir, Y.; Zhang, W.; Basso, B.; Smucker, A. J. M., Development of a new long-term drought resilient soil water retention technology. Journal of Soil and Water Conservation 2014, 69, (5), 154A-160A. 33. Kelly, J. G.; Han, F. X.; Su, Y.; Xia, Y.; Philips, V.; Shi, Z.; Monts, D. L.; Pichardo, S. T.; Xia, K., Rapid Determination of Mercury in Contaminated Soil and Plant Samples Using Portable Mercury Direct Analyzer Without Sample Preparation, a Comparative Study (vol 223, pg 2361, 2012). Water Air and Soil Pollution 2014, 225, (7). 34. Khatiwada, R.; Hettiarachchi, G. M.; Mengel, D. B.; Fei, M., Placement and Source Effects of Phosphate Fertilizers on Phosphorus Availability and Reaction Products in Two Reduced-Till Soils: A Greenhouse Study. Soil Science 2014, 179, (3), 141-152. 35. Knappenberger, T.; Flury, M.; Mattson, E. D.; Harsh, J. B., Does Water Content or Flow Rate Control Colloid Transport in Unsaturated Porous Media? Environmental Science & Technology 2014, 48, (7), 3791-3799. 36. Knote, C.; Hodzic, A.; Jimenez, J. L.; Volkamer, R.; Orlando, J. J.; Baidar, S.; Brioude, J.; Fast, J.; Gentner, D. R.; Goldstein, A. H.; Hayes, P. L.; Knighton, W. B.; Oetjen, H.; Setyan, A.; Stark, H.; Thalman, R.; Tyndall, G.; Washenfelder, R.; Waxman, E.; Zhang, Q., Simulation of semi-explicit mechanisms of SOA formation from glyoxal in aerosol in a 3-D model. Atmospheric Chemistry and Physics 2014, 14, (12), 6213-6239. 37. Kravchenko, A. N.; Negassa, W.; Guber, A. K.; Schmidt, S., New Approach to Measure Soil Particulate Organic Matter in Intact Samples using X-Ray Computed Microtomography. Soil Science Society of America Journal 2014, 78, (4), 1177-1185. 38. Kravchenko, A. N.; Robertson, G. P., Whole-Profile Soil Carbon Stocks: The Danger of Assuming Too Much from Analyses of Too Little (vol 75, pg 235, 2011). Soil Science Society of America Journal 2014, 78, (4), 1491-1491. 39. Li, M.; Toner, B. M.; Baker, B. J.; Breier, J. A.; Sheik, C. S.; Dick, G. J., Microbial iron uptake as a mechanism for dispersing iron from deep-sea hydrothermal vents. Nature Communications 2014, 5. 40. Li, T.; Tao, Q.; Liang, C.; Shohag, M. J. I.; Yang, X.; Sparks, D. L., Complexation with dissolved organic matter and mobility control of heavy metals in the rhizosphere of hyperaccumulator Sedum alfredii. Environmental Pollution 2013, 182, 248-255. 41. Ma, Y.; Zheng, X.; Anderson, S. H.; Lu, J.; Feng, X., Diesel oil volatilization processes affected by selected porous media. Chemosphere 2014, 99, 192-198. 42. Mainelis, G.; Seshadri, S.; Garbuzenko, O. B.; Han, T.; Wang, Z.; Minko, T., Characterization and Application of a Nose-Only Exposure Chamber for Inhalation Delivery of Liposomal Drugs and Nucleic Acids to Mice. Journal of Aerosol Medicine and Pulmonary Drug Delivery 2013, 26, (6), 345-354. 43. Mejias, J. H.; Alfaro, M.; Harsh, J., Approaching environmental phosphorus limits on a volcanic soil of Southern Chile. Geoderma 2013, 207, 49-57. 44. Miller, J. O.; Karathanasis, A. D., Biosolid Colloids as Environmental Contaminant Carriers. 2014; p 1-18. 45. Nazarenko, Y.; Lioy, P. J.; Mainelis, G., Quantitative assessment of inhalation exposure and deposited dose of aerosol from nanotechnology-based consumer sprays. Environmental Science-Nano 2014, 1, (2), 161-171. 46. Ortega, J.; Turnipseed, A.; Guenther, A. B.; Karl, T. G.; Day, D. A.; Gochis, D.; Huffman, J. A.; Prenni, A. J.; Levin, E. J. T.; Kreidenweis, S. M.; DeMott, P. J.; Tobo, Y.; Patton, E. G.; Hodzic, A.; Cui, Y. Y.; Harley, P. C.; Hornbrook, R. S.; Apel, E. C.; Monson, R. K.; Eller, A. S. D.; Greenberg, J. P.; Barth, M. C.; Campuzano-Jost, P.; Palm, B. B.; Jimenez, J. L.; Aiken, A. C.; Dubey, M. K.; Geron, C.; Offenberg, J.; Ryan, M. G.; Fornwalt, P. J.; Pryor, S. C.; Keutsch, F. N.; DiGangi, J. P.; Chan, A. W. H.; Goldstein, A. H.; Wolfe, G. M.; Kim, S.; Kaser, L.; Schnitzhofer, R.; Hansel, A.; Cantrell, C. A.; Mauldin, R. L.; Smith, J. N., Overview of the Manitou Experimental Forest Observatory: site description and selected science results from 2008 to 2013. Atmospheric Chemistry and Physics 2014, 14, (12), 6345-6367. 47. Park, J. H.; Fares, S.; Weber, R.; Goldstein, A. H., Biogenic volatile organic compound emissions during BEARPEX 2009 measured by eddy covariance and flux-gradient similarity methods. Atmospheric Chemistry and Physics 2014, 14, (1), 231-244. 48. Pusede, S. E.; Gentner, D. R.; Wooldridge, P. J.; Browne, E. C.; Rollins, A. W.; Min, K. E.; Russell, A. R.; Thomas, J.; Zhang, L.; Brune, W. H.; Henry, S. B.; DiGangi, J. P.; Keutsch, F. N.; Harrold, S. A.; Thornton, J. A.; Beaver, M. R.; St Clair, J. M.; Wennberg, P. O.; Sanders, J.; Ren, X.; VandenBoer, T. C.; Markovic, M. Z.; Guha, A.; Weber, R.; Goldstein, A. H.; Cohen, R. C., On the temperature dependence of organic reactivity, nitrogen oxides, ozone production, and the impact of emission controls in San Joaquin Valley, California. Atmospheric Chemistry and Physics 2014, 14, (7), 3373-3395. 49. Rabolt, J. F.; Tang, W.; Chase, D. B.; Sparks, D. L. Nanocomposite structure for sensor, has outermost third polyelectrolyte layer that is disposed on each gold nanorod of charged nanorod, and having change that is opposite charge of second polyelectrolyte. WO2014159521-A1. 50. Ramagopal, M.; Wang, Z.; Black, K.; Hernandez, M.; Stambler, A. A.; Emoekpere, O. H.; Mainelis, G.; Shalat, S. L., Improved exposure characterization with robotic (PIPER) sampling and association with children's respiratory symptoms, asthma and eczema. Journal of Exposure Science and Environmental Epidemiology 2014, 24, (4), 421-427. 51. Sang, W.; Stoof, C. R.; Zhang, W.; Morales, V. L.; Gao, B.; Kay, R. W.; Liu, L.; Zhang, Y.; Steenhuis, T. S., Effect of Hydrofracking Fluid on Colloid Transport in the Unsaturated Zone. Environmental Science & Technology 2014, 48, (14), 8266-8274. 52. Sankar, M. S.; Vega, M. A.; Defoe, P. P.; Kibria, M. G.; Ford, S.; Telfeyan, K.; Neal, A.; Mohajerin, T. J.; Hettiarachchi, G. M.; Barua, S.; Hobson, C.; Johannesson, K.; Datta, S., Elevated arsenic and manganese in groundwaters of Murshidabad, West Bengal, India. Science of the Total Environment 2014, 488, 574-583. 53. Sarkar, S.; Zhang, L.; Subramaniam, P.; Lee, K.-B.; Garfunkel, E.; Strickland, P. A. O.; Mainelis, G.; Lioy, P. J.; Tetley, T. D.; Chung, K. F.; Zhang, J.; Ryan, M.; Porter, A.; Schwander, S., Variability in Bioreactivity Linked to Changes in Size and Zeta Potential of Diesel Exhaust Particles in Human Immune Cells. Plos One 2014, 9, (5). 54. Sarkar, S.; Zhang, L.; Subramaniam, P.; Lee, K.-B.; Garfunkel, E.; Strickland, P. A. O.; Mainelis, G.; Lioy, P. J.; Tetley, T. D.; Chung, K. F.; Zhang, J.; Ryan, M.; Porter, A.; Schwander, S., Variability in bioreactivity linked to changes in size and zeta potential of diesel exhaust particles in human immune cells. PloS one 2014, 9, (5), e97304-e97304. 55. Senaviratne, G. M. M. M. A.; Udawatta, R. P.; Anderson, S. H.; Baffaut, C.; Thompson, A., Use of Fuzzy rainfall-runoff predictions for claypan watersheds with conservation buffers in Northeast Missouri. Journal of Hydrology 2014, 517, 1008-1018. 56. Senaviratne, G. M. M. M. A.; Udawatta, R. P.; Baffaut, C.; Anderson, S. H., Evaluation of a Stepwise, Multiobjective, Multivariable Parameter Optimization Method for the APEX Model. 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W.; Xiong, X., Wetting Agent Influence on Water Infiltration into Hydrophobic Sand: II. Physical Properties. Agronomy Journal 2014, 106, (5), 1879-1885. 62. Stucki, J. W.; Su, K.; Pentrakova, L.; Pentrak, M., Methods for handling redox-sensitive smectite dispersions. Clay Minerals 2014, 49, (3), 359-377. 63. Subroy, V.; Gimenez, D.; Qin, M.; Krogmann, U.; Strom, P. F.; Miskewitz, R. J., Hydraulic properties of coarsely and finely ground woodchips. Journal of Hydrology 2014, 517, 201-212. 64. Syswerda, S. P.; Corbin, A. T.; Mokma, D. L.; Kravchenko, A. N.; Robertson, G. P., Agricultural Management and Soil Carbon Storage in Surface vs. Deep Layers (vol 75, pg 92, 2011). Soil Science Society of America Journal 2014, 78, (4), 1489-1489. 65. Tamir, G.; Shenker, M.; Heller, H.; Bloom, P. R.; Fine, P.; Bar-Tal, A., Organic N mineralization and transformations in soils treated with animal waste in relation to carbonate dissolution and precipitation. Geoderma 2013, 209, 50-56. 66. 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