SAES-422 Multistate Research Activity Accomplishments Report
Sections
Status: Approved
Basic Information
- Project No. and Title: W82 : Reducing the Potential for Environmental Contamination by Pesticides and Other Organic Chemicals
- Period Covered: 01/01/2001 to 12/01/2001
- Date of Report: 02/07/2002
- Annual Meeting Dates: 01/09/2002 to 01/10/2002
Participants
Watson, Jack (jackwatson@psa.edu) - Penn State University; Schmidt, Walter (schmidtw@ba.ars.usda.gov) - USDA-ARS, Beltsville, MD; Sadowsky, Mike (sadowsky@soils.umn.edu) - University of Minnesota; Radosevich, Mark (mrad@udel.edu) - University of Delaware; Feng, Yucheng (yfeng@acesag.auburn.edu) - Auburn University; Ray, Chittaranjan (cray@hawaii.edu) University of Hawaii; Lee, Linda (lslee@purdue.edu) - Purdue University; Senseman, Scott (s-senseman@tamu.edu) - Texas A&M University; Evangelou, Bill (revangel@iastate.edu) - Iowa State University; Koskinen, Bill (koskinen@soils.umn.edu) - USDA-ARS, St. Paul, MN; Knighton, Ray (rkinghton@reeusda.gov) USDA- CSREES, Washington, D.C.; Boyd, Steven (Boyds@msa.edu) - Michigan State University; Li, Hui (lihui@msu.edu) - Michigan State University; Clay, Sharon (Sharon_clay@sdstate.edu) - South Dakota State University
Accomplishments
Research accomplishments have centered on (1) expanding fundamental knowledge of the processes by which pesticides and other toxic organics interact in soil-water-air systems, (2) coupling and integrating these processes into useful predictive models describing the fate of chemicals in the environment, and (3) assessing various agronomic and management practices for either preventing pollution or improving remediation strategies.
Objective 1. Characterize and quantify the basic chemical and biological processes controlling the behavior of pesticides, other organic chemical, and microorganisms in soil, water and air.
This objective includes studies on the fate and transport of organic contaminants in soil, water, and air. Specific areas of progress for 2001 are summarized below:
Bioavailability of Soil-sorbed Atrazine (Auburn University)
Atrazine Degradation on Manganese Oxides (University of California - Berkely)
Redox Properties of Humic Acids for Development of Abiotic and Biological Pathways for Herbicide Remediation (University of California - Berkely)
Bioremediation of MTBE (University of California-Davis).
Impact of Methyl Bromide and 1,3-dichloropropene on Soil Microbial Communities (USDA-ARS, Salinity Lab, Riverside, CA).
Degradation of Soil Fumigants as affected by Initial Concentration and Temperature (USDA-ARS, Salinity Lab, Riverside, CA).
Evaluation of Propargyl Bromide for Control of Barnyardgrass and Fusarium oxysporum in Three Soils. (USDA-ARS, Salinity Lab, Riverside, CA).
Microcosm Enrichment of 1,3-dichlorpropene-degrading Soil Microbial Communities in a Compost-amended Soil. (USDA-ARS, Salinity Lab, Riverside, CA).
Environmental Conditions Influence on Permeability of Plastic Films to Fumigant Vapors (USDA-ARS, Salinity Lab, Riverside, CA).
Transformation of Propargyl Bromide in Soil (USDA-ARS, Salinity Lab, Riverside, CA).
Role of Pi-Pi Interactions Between Organic Compounds and Humic Substances (Connecticut Agricultural Experiment Station, New Haven).
Influence of Sorbate Structure on Nonideal Sorption Behavior of Organic Chemicals in Soil Organic Matter (Connecticut Agricultural Experiment Station, New Haven).
Microbial Community Response to Repeated s-Triazine Exposure and Nutrient Availability: Linking Community Structure and Pesticide Degradation Capacity (University of Delaware). Phenanthrene Degradation In Soils Co-inoculated with Phenanthrene-degrading and Biosurfactant-producing bacteria. (University of Delaware).
Bacteriophage Diversity and Transduction Potential in Agricultural Soils. (University of Delaware).
Occurrence, Distribution, and Fate of Nonylphenol Polyethoxylates and 4-Nonylphenol in Northeast Kansas Wastewater Treatment Plants (Kansas State University)
Uptake of Ethylene Dibromide (EDB) by Cranberry (Vaccinium macrocarpon) Plants (Kansas State University)
Sorption of Acidic Pesticides on Variable-Charge Soils (Purdue University)
Sorption of Polycyclic Aromatic Hydrocarbons (PAHs) (Purdue University)
Fate of Benomyl Degradation Products in Soil (Purdue University)
Fate of Animal Pharmacueticals and E. coli from Swine Manure (Purdue University)
Phytoremediation of Contaminated Soil (Purdue University)
Microbial Functional and Phylogenetic Diversity in Contaminated Sites (Purdue University)
Atrazine Reactions with Clay Mineral Surfaces in the Presence of Nonionic Surfactants (Iowa State University)
Confined Chemistry of Monovalent/Divalent Cations in Smectitic Alluvial Soils (Iowa State University)
Monovalent Cation Confinement by Smectites and Critical Salt Dispersion Thresholds (Iowa State University)
Ammonium-calcium Exchange in the Absence and Presence of Potassium on Vermiculite and Hydroxy-Al Vermiculite (Iowa State University)
Surface Chemistry and Function of Microbial Biofilms (Iowa State University)
Sorption-desorption of ?Aged? Sulfonylaminocarbonyltriazolinone Herbicides and Metabolites in Soil (USDA-ARS, St. Paul, MN)
Sorption of Two New Sulfonylaminocarbonyltriazolinone Herbicides and Their Metabolites on Organic and Inorganic Exchanged Smectites (USDA-ARS, St. Paul, MN)
A Novel Psba1 Gene from a Naturally-occurring Atrazine-resistant Cyanobacterial Isolate (University of Minnesota)
Complete Nucleotide Sequence and Organization of the Atrazine Catabolic Plasmid Padp-1 from Pseudomonos Sp. Strain ADP (University of Minnesota)
Melamine Deaminase and Atrazine Chlorohydrolase: 98% Identical but Functionally Different. (University of Minnesota)
Microbial Degradation of s-Triazine Herbicides (University of Minnesota)
Physical and Chemical Properties and Interactions on Interfacial Non-soil Surfaces ? Molecular and Chemical Mechanisms (USDA-ARS, Beltsville, MD)
Characterize the Distribution, Dissipation, and Efficacy of Pesticides on Wind-erodible Sediments Using Field and Laboratory Studies (South Dakota State University)
Objective 2. Integrate chemical and biological process information for use in models applicable across different spatial and temporal scales.
W-82 project participants used models in various stages of research reported under objective 1 and 3. Specific areas of 2001 progress in which modeling played a prominent role are summarized below:
Sorption Kinetics of Organic Compounds in Soil Organic Matter. Development and Application of Polymer-based Diffusion Model. (Connecticut Agricultural Experiment Station, New Haven).
Sorption Kinetics of Organic Compounds in Soil Organic Matter. Concentration Dependence of Normalized Rates (Connecticut Agricultural Experiment Station, New Haven).
Simulation of Contaminant Transport in Macroporous Media Using Dual-permeability Approach for Flow, Depth Variant Sorption and Domains Specific Degradation (University of Hawaii)
Simulation of Contaminant Transport from Surface Water to Wells located on Riverbanks During Flood Periods (University of Hawaii)
Spatial Variability of Atrazine and Alachlor Efficacy and Mineralization in an Eastern South Dakota Field (South Dakota State University)
Predicting Pesticide Volatilization from Soils (USDA-ARS, Salinity Lab, Riverside, CA). Modeling Transport of Volatile Organic Chemicals in Unsaturated Layered Systems (USDA-ARS, Salinity Lab, Riverside, CA).
Objective 3. Provide stakeholders with tools for developing strategies to ensure sustainable agriculture and to protect natural resource systems.
Development of management practices which greatly reduce off-site transport of and worker exposure to fumigants including application of amendments and virtually impermeable film to the soil surface. (USDA-ARS Salinity Laboratory, California)
Assessment of the Vulnerability of Farmstead and Rural Domestic Wells to Agrichemical Contamination (University of Hawaii)
Post-audit Study of Ethylenedibromide (EDB) and Dibromochloropropane (DBCP) Transport in the Pearl Harbor Aquifer System (University of Hawaii)
Chemical Leaching and Evaluation of Risk System (University of Hawaii)
Demonstration of Bromacil Leaching Under Reduced Application Rates (University of Hawaii)
Monitoring of Pesticide Impaired Lakes in Texas and the Use of Buffer Strips to Limit Contamination (Texas A&M)